The relative velocity is 20 m/s. How does the "20 m/s faster" come into play? Is it 100 m/s-80 m/s? Is it 392 m/s 372m/s?? What are the two velocities of the two cars?? There must be two different velocities if one car is 20 m/s faster than the other car!!
If there are only two cars, then the difference is 20 m/s - 0 m/s.
The first car is sitting still and the second car is moving away at 20 m/s.