chinglu, (taking some licence) SR asserts that the laws of physics hold as true for all inertial frames of reference, as "The Principle of Relativity" and raises it to the level of a postulate.
The ECEF and ECI frames are not inertial relative to one another.
An ECI frame can be treated as an inertial frame within which the earth is centered, but the earth in that case which spins on its axis within that frame is not itself inertial... And both, the ECI frame and the earth, if viewed from some more distant point are moving (orbiting) the sun and are thus neither from that perspective inertial.
An ECEF frame sets the earth as an inertial object at its center and the coordinate system rotates around a fixed point at the Earth's center of mass, such that all points on the surface of the earth have fixed coordinates.
These are two different coordinate systems. Each could be considered as inertial from some frame of reference, but they are not both inertial from any one frame of reference... And they both exist within the context of general relativity, spacetime and gravity, where except within suficiently local limits, SR does not apply.
They are not equivalent.., and yet yes one can transform coordinates between the two. But think it through, an object at rest in one frame will be accelerating in the other and visa versa. Think about it. Besides objects are inertial or not, coordinate systems are abstract systems used to define and describe the relationships and motions of objects. They can be inertial only to the extent they are attached to an object that is inertial, or to the extent they describe an inertial relationship between two or more objects.