Polyethylene is a polymer, which is loosely analogous to a train composed of hundreds of separate cars linked together. Polyethylene is made using chain reaction starting with units called monomers. The monomer of polyethylene is ethylene, which is a class 3 carcinogen.
The most common way to make polyethylene is via a free radial polymerization where you use an initiator to react with ethylene. The ethylene binds with the initiator and then becomes the free radial source for the next ethylene to link into the chain, etc. Based on the concentration of initiator you can control how many polymer chains forms and the viscosity of the final plastic. More initiator makes more chains of smaller length resulting in lower viscosity. This might make it easier for extrusion fabrication.
The potential health problems are connected to residual initiator in the final product since these can still generate free radials. It is also connected to possible active ends that still exist on the polymers when ethylene funds out. The active ends can assist reversal reactions generating traces of ethylene.
Personally, I never understood the logic for carrying water around if you are not exercising and sweating. What natural animals drink even when not thirsty?This is all artificial. But then I realizes the free market needs sheep to shear. Also why people would pay 100 times the value of water if it is in a bottle. Again, free marketing is a wonderful way to lead the herd to the pen for shearing.