You're being disingenius, illiterate, or incoherent, and I can't decide which it is, and here's why:i assume you meant the link to the PDF you mentioned.
came from NASA and has not been independently verified.
it also didn't state it would apply to all the amino acids in the body.
it did mention a few though.
Let's start off by repeating what you said:
i assume you meant the link to the PDF you mentioned.
came from NASA and has not been independently verified.
it also didn't state it would apply to all the amino acids in the body.
it did mention a few though.
Now, this was in response to this:
Now go back and re-read what I actually said.
Which was my response to this:
you only provided the source for one compound.
i believe there are 20 amino acids that needs the similar treatment.
can they all be separated by circulatory polarized light?
Which was in response to this:
Quite, and meanwhile he (and leopold) just side step the issue that we have direct evidence of handedness arising naturally, and early.
Which was referring back to this post:
I'm going to reiterate here a point I made in another thread:
Trippy 2775021/59Again, this issue is a non-starter.
Carbon rich meteorites have been found to have an excess of L-Enantiomers over D-Enantiomers in carbon rich meteorites, and there are several explanations that have been proposed for this observation - including circularly polarized light as a result of supernovae.
However, recently, the observation was made that the greater the enrichment of L-isovaline in these meteorites, the greater the amount of water alteration that appeared to have taken place. This is important to note because, at least in the case of isovaline, L-isovaline is slightly less soluble in water than D-isovaline.
Here is a paper from 2009 discussing the discovery of excess L-Isovaline in the Murchison Meteorite and the Orgueil Meteorite.
Enrichment of the amino acid L-isovaline by aqueous alteration on CI and CM meteorite parent bodies
And here's a NASA press release (there will be a paper associated with it somewhere, I simply lack the time to track it down) that exteds the initial findings to a wider range of meteorites.
More Asteroids Could Have Made Life's Ingredients
So, like the fixable nitrogen issue, this issue is a non-starter. You'll also note that there's an extra added layer of parsimony in all of this (to put it one way) in that the excess of L-Amino acids has come from the same source as the ammonia - indeed, they've both been found in the same meteorite.
Which brings us back to the full circle, and asking whether you're a liar or a moron.
Observe.
First let's break down the post in question:
Again, this issue is a non-starter.
Carbon rich meteorites have been found to have an excess of L-Enantiomers over D-Enantiomers in carbon rich meteorites, and there are several explanations that have been proposed for this observation - including circularly polarized light as a result of supernovae.
Okay, that's fine, here I mention that meteorites have, for a long time been known to have an excess of one enatiomer over another, and it happens to be the same enantiomer that earth bound life forms use, then I suggest that a number of explanations have been proposed, one of which is cirularly polarized high energy photons from a supernova. Which I clarify again later in response to one of your posts:
First off, it's circularly polarized light, circulatory polarized light is a meaningless term, and yes, it would affect all amino acids, that's one of the reasons it was proposed as a mechanism.
We have other lines of evidence suggesting a nearby supernova very early in the earth's history, and a nearby supernova would affect all amino acids, and have the capability to 'process' the entire solar system at once.
And then I continue:
Oooh, exciting, here I'm discussing new science, recent discoveries - in these meterorites, which display this excess, we find that the areas that have the greatest enrichment, also show the greatest amount of alteration by water - NOT alteration by high energy photons such as those found in a supernova, but alteration by water.However, recently, the observation was made that the greater the enrichment of L-isovaline in these meteorites, the greater the amount of water alteration that appeared to have taken place.
Then I explain, in the most succinct fashion I can think of why this is important:
It's important because the enantiomer that life doesn't use, is more soluble in water than the enantoimer that life does use. Incidentally, we're not talking an enrichment of a few percent here, we're talking a thousand fold enrichment. Note that I'm talking about solubility in water, not rates of photodissociation by circularly polarized light.This is important to note because, at least in the case of isovaline, L-isovaline is slightly less soluble in water than D-isovaline.
You'll also note the use of some weasel wording in there, I know, for a fact, that it's true of isovaline, because I took the time to exercise due dilligence and looked up the solubility of isovaline on solubility tables, and found that one is slightly more soluble in water than the other.
Both are soluble in water, so as you deplete one, you deplete them both, however you deplete the more soluble one more than you deplete the less soluble one.
Here I provide a link to a two year old paper, that IIRC goes somewhat in depth into various amino acids, but only looks at a couple of meteorites - this is important, because it extrapolates the findings beyond isovaline, and pre-empts the argument 'But it's just the one, it could be special in some way'. Note that the title of the paper says 'aqueous alteration' not 'photodissociation'.Here is a paper from 2009 discussing the discovery of excess L-Isovaline in the Murchison Meteorite and the Orgueil Meteorite.
Enrichment of the amino acid L-isovaline by aqueous alteration on CI and CM meteorite parent bodies
Aqueous: a term used to describe a system which involves water.
Here I provide a link to a press release that discusses a new finding that is related to the 2009 paper, that studies a wider range of of meteorite types, and finds an excess in those, and finds the same correlation between the degree of water alteration, and the degree of enrichment. Again, that's water alteration, not photodissociation, and not irradiation.And here's a NASA press release (there will be a paper associated with it somewhere, I simply lack the time to track it down) that exteds the initial findings to a wider range of meteorites.
More Asteroids Could Have Made Life's Ingredients
Here I suggest that the 'asteroid seeding' hypothesis has (or should have) an added level of appeal to it, because it solves more than one problem with a single hypothesis - implicit in this is the assumption (or explicit context in the original thread) that the reader is smart enough to figure out for themselves that if the amines found on earth came from asteroids, and the amines on asteroids have an excess of one enantiomer over another, then it stands to reason that the earth should have the same excess. The significance of which requires the prior knowledge that with one or two exceptions, none of which IIRC are relevant here, the rate of a reaction is dependent on the concentration of the reactants (as well as, in some cases, the concentration of the products), which has the corrollary that if there is an excess of one enantiomer over another in the initial mixture, then one reaction will 'out compete' the other.So, like the fixable nitrogen issue, this issue is a non-starter. You'll also note that there's an extra added layer of parsimony in all of this (to put it one way) in that the excess of L-Amino acids has come from the same source as the ammonia - indeed, they've both been found in the same meteorite.
Now, getting back to your post, which I will repeat again:
i assume you meant the link to the PDF you mentioned.
came from NASA and has not been independently verified.
it also didn't state it would apply to all the amino acids in the body.
it did mention a few though.
An again, but this time with the added context of nested quotes:
i assume you meant the link to the PDF you mentioned.you only provided the source for one compound.
i believe there are 20 amino acids that needs the similar treatment.
can they all be separated by circulatory polarized light?
Now go back and re-read what I actually said.
came from NASA and has not been independently verified.
it also didn't state it would apply to all the amino acids in the body.
it did mention a few though.
The PDF I provided had nothing to do with circularly polarized light. The PDF has to do with the alteration of amino acids by water, not the photodissociation of amino acids by circularly polarized light, or to do with supernovae.
Now before I go any further, I do have one confession to make - I may have inadvertantly conflated two seperate theories, however, we come back to the same point - if I had been intending to illustrate supernova initiated refractory processes leading to enantiomeric enrichment, I would have linked to one of Boyd et al's papers - eg this one or this one, or if I was wanting to discuss 'one handed' enrichment of DNA or RNA by circularly polarized light I would have linked to Michaelin's paper.
But I didn't, I linked to things discussing the evidence for enrichment by preferential dissolution in meteorites. Which leads us back to my opening question, given that the material I linked to discusses enrichment of seeding material by preferential dissolution, why are you asking me if photodissociation by circularly polarized light is applicable to all amino acids because (And here I quote you, and paraphrase you) "...the PDF mentioned... ...didn't state it would apply to all the amino acids in the body." Are you inept and unable to express youself clearly? I.E. Am I somehow supposed to infer that even though we've been discussing photodissociation, and the context the statement was made in was one of a discussion of photodissociation, that you now wish to discuss enrichment by preferential dissolution, but you're unable to formulate a clear statement such as 'one question about the water thing'? Are you illiterate, or do you have some kind of short term memory issue that means you're unable to retain the context of a dicussion for the duration of the discussion, even though you have only recently looked at the initial post in question? Or are you dishonest and forwarding an allegation or hypothesis that you know to be untrue, or engage me in a 'bait and switch' by engaging me in one topic, and then suddenly, without anything approaching an indication, changing subject in the hope to trick me into making some kind of gaff?