Here is what Glasby actually said about abiotic formation in the upper mantle:
“…A key point is the role of hydrogen generated by the Fischer-Tropsch reaction in the formation of abiogenic hydrocarbons (Holm and Charlou, 2001). However, the error in this statement, as we shall see later, lies in the fact that
the upper mantle is too oxidizing to permit methane to be the dominant form of carbon there. [sze=4]It is for this reason that
commercial-grade petroleum deposits could not have formed abiogenically[/size].…”
From page 88 end of first column of Gasby’s review paper in highly respected
RESOURCE GEOLOGY, vol. 56, no. 1, 85–98, 2006
See it fro free at:
http://static.scribd.com/docs/j79lhbgbjbqrb.pdf
I.e. the Fischer-Tropsch reaction, which is necessary for the transformation of hydrogen (and CO2) into methane can take place in the mantle but formation of significant abiogenic oil is impossible there as it is too oxidizing for the methane to survive there. Thus, it is the ABIOTIC theory that is impossible as it requires free hydrogen and /or methane be produced for the inorganic compounds water, H2O and carbonate rocks and/or CO2. In other words, even if hydrogen and/or methane were produced, it would rapidly be re-oxidized.
At the start of the discussion section, column 1 page 92, Glasby restates this as follows:
“…{abiotic origin} arguments presented by Kenney et al. (2002) do represent a rigorous interpretation of the thermodynamic data. However, the formation of higher hydrocarbons from methane in the upper mantle is only one link in the chain of petroleum formation. Perhaps the clearest argument against the abiogenic theory is the oxidation state of the mantle. …”: