Thanks. Here are a few "information gems" one of their papers has (from :
http://nh3fuel.files.wordpress.com/2012/10/shroder-carl.pdf):
Sun supplies to earth surface over 2000 thousand TW-hrs/day and man´s daily total energy use was (in 2008) about 363 TW-hrs/day. Note >2000E3/363 = >5,510
For most terrestrial uses it is the energy per unit volume that is most important. Here are some of interest as a percent of the diesel, the highest, at 138,490 BTU / gallon: Diesel,100 Gasoline,89.8 Propane,66.0 Ethanol,61.0 Mehanol,45.1 Ammonia,43.5 Highest Li-ion battery,< 3.0 Liquid (very cold) H2,25.9 H2 at STP, <0.001
The liquid ammonia / liquid H2 hydrogen content ratio is: 43.5 / 25.9 = 1.68; So my prior statement, from memory, of about 1.30 is grossly unfair to ammonia.
Note liquid H2 requires refrigeration and storage at nearly absolute zero temperate, while liquid NH3 needs only very modest compression and no cooling.
Ammonia is by far the best way to transport hydrogen, and tons of it are safely transported every day (on annual average) for use on farms as fertilizer.
The H2 powered fuel cell car has efficiencies of: 23% (compressed H2) & 19% (Liquid H2) vs. 69% for an EV car or 31% for the sugarcane ethanol IC engine car.* (Note sugarcane´s energy input is 87% free! So its lower efficiency vs. the electric car is not important.)
http://phys.org/news85074285.html#jCp said:
The large amount of energy required to isolate hydrogen from natural compounds (water, natural gas, biomass), package the light gas by compression or liquefaction, transfer the energy carrier to the user, plus the energy lost when it is converted to useful electricity with fuel cells, leaves an unacceptable value to run an economy in a sustainable future. Only niche applications like submarines and spacecraft might use hydrogen.
A 100 MWh (or Mjoules) of energy in both ammonia and or ethanol can be produced many times (at least twice - I´ll try to find and edit with exact data) lower cost than production of same energy produced in Hydrogen.
SUMMARY: The H2 fueled car (1) has much lower energy efficiency, is (2) much more expensive, and is (3) many times more dangerous than at least two well
demonstrated alternatives with no damage to the environment! (H2 does, until US electric power is 100% solar) (4) Thus, hydrogen fueled car releases CO2.
Hydrogen will never be used for transport fuel. "Four strikes and you are out!" (I give
thedoctor an extra strike, but bet he cannot change his false beliefs.)
*Sugarcane ethanol has RoE = 8. Or is > 87% efficient. In a well designed IC engine it is >35% energy efficient. Thus over all efficiency is > 0.87 x 0.35 = >31%
Note also: Ammonia can be made from sunshine, water and air - inexhaustive sources too as when burned in IC engine, the water and N2 are returned to the air.
Either ammonia or sugarcane ethanol is MUCH more cost attractive, sustainable, environmental friendly, fuel for cars than hydrogen, and ALWAYS will be;
however, ammonia is toxic, must be compressed to be liquid, and does not have 35+ years of large scale demonstrated use as a car fuel, so I prefer sugarcane ethanol for all world´s cars using liquid fuel. The land required for growing that much sugarcane is about 1% of earth´s arable land.
Later by edit: Happened across fact that electrolysis require ~13.5Mj/kg of H2 (if memory of a few hours is OK). Article was noting that energy could be partly heat. I.e. 1000 degree steam, being split into H2 & O2, cut the electrical requirement by ~30%, but I seriously doubt that is useful. That is one hell of an expensive high presures to play around with and it you have it, why not make electric power? I had long ago the idea that electolysis at home could run to make high presure H2 with no need for a compressor - but it will take more electrical energy (no free lunch) and if not producing just a tiny volume per minute when you disconnet the line to the car, significant energy is lost as the presure in line and electrolsis unit falls. Also what use would I have for O2 at high pressure?