Link from the NIH:
http://toxtown.nlm.nih.gov/text_version/chemicals.php?id=6
"Carbon dioxide in its gas form is an asphyxiant, which cuts off the oxygen supply for breathing, especially in confined spaces. Exposure to concentrations of 10 percent or more of carbon dioxide can cause death, unconsciousness, or convulsions. Exposure may damage a developing fetus.
Exposure to lower concentrations of carbon dioxide can cause hyperventilation, vision damage, lung congestion, central nervous system injury, abrupt muscle contractions, elevated blood pressure, and shortness of breath. Exposure can also cause dizziness, headache, sweating, fatigue, numbness and tingling of extremities, memory loss, nausea, vomiting, depression, confusion, skin and eye burns, and ringing in the ears. "
Inspectapedia:
http://www.inspectapedia.com/hazmat/CO2gashaz.htm
"This is important because we recently had an accident with CO2 in Sweden killing two persons. According to the newspapers CO2 is nontoxic and it is the decreased oxygen levels that kills. Using the equation above one can quickly conclude that adding 31 liters of CO2 would result in 24% CO2(almost instantly fatal) and 16% oxygen (equivalent with breathing at 2800 meters above sea level, which is not dangerous). In conclusion, it is the toxic properties of CO2 that is fatal, not the drop in oxygen."